Inhibiting effects by Fe2O3 on combustion and explosion characteristics of ABS resin

The global increase in the use of, and reliance on, plastics has prompted the demand for acrylonitrile-butadiene-styrene (ABS) resin in various fields. With this increased requirement, numerous failures have occurred in the ABS process. Those incidents, resulting from electrostatic discharge, powder accumulation, heat accumulation, construction sparks, and plant fires, have caused dust fire and explosions.In this study, the ABS resin was gleaned from the site and tested for its explosion parameters, including minimum ignition temperature of dust cloud (MIT_C), minimum ignition energy (MIE), and minimum explosion concentration (MEC). To improve loss prevention in the manufacturing process, ferric oxide (Fe₂O₃) as an inert additive was added in the ABS powder. According to the MIE test, Fe₂O₃ has an apparent inhibiting effect on dust explosion for the ABS dust. With the proportion of Fe₂O₃ increased from 25 to 50 mass% in ABS, the MIE increased from 67 to 540 mJ. The explosion tests via 20-L apparatus indicated that Fe₂O₃ mixed with ABS could not increase the MEC significantly. However, the explosion pressure dropped by increasing in the ratio of Fe₂O₃ in ABS. This inerting strategy of ABS was deemed to substantially lessen the probability and severity of fire and explosion.     

Assessment of the effect of technical and management characteristics on the frequency of release from piping: An application to a gas storage facility

The assessment of the frequencies of release from piping due to losses of containment is an essential step in the preparing Safety Reports, drawn up as required by the so-called “Seveso” Directive. These are usually calculated starting from the frequencies of random rupture included in international databases and are not plant-specific, furthermore, the quantification of the effect of the safety management system of the facility is not easy. A simple and flexible approach quantifying technical and management characteristics of the plant has been proposed by Milazzo and co-workers in 2010; it is based on the modification of the frequency taken from literature, through the use of the percentages of failure causes actually possible in that plant, and the judgment about their management. The data about the failure causes are taken from the literature and modified by using corrective factors to adapt them to the industrial context. To make possible the application of the method to a large number of major-hazard industry types, some aspects of the approach needed to be improved; these have been identified during a development project coordinated by RINA Consulting, on behalf of Saipem, with the collaboration of the University of Messina. The improvement of the approach focused on two main points, the development of a method to calculate the corrective factors for the failure causes associated with corrosion and erosion phenomena and the strengthening of the methodology for the formulation of the judgment about the safety management. This paper illustrates the fully improved method, as well as an application to a typical gas storage plant.     

高效复合菌在木薯酒精废液处理中的应用研究

对酒精废液生物处理反应器内颗粒污泥中的微生物进行分离纯化.分离出的8株高效优势菌,初步鉴定结果:1号为皮杆菌属;2号为棒杆菌属;3号、4号为微小杆菌属;5号为乳杆菌属;6号为纤维单胞菌属;7号为丙酸杆菌属;8号为红长命菌属.对8种纯化后的菌株进行混合培养,确定了复合菌群生长最佳培养温度为37℃,最适pH值为6.8.在处理过程中投加适量葡萄糖、硝酸铵和微量元素能够提高复合菌群的处理效果.最佳添加量为:葡萄糖0.5g/L,硝酸铵1g/L,Fe2 5mg/L和Ca2 25mg/L.在日处理量100 m3的UASB生物反应器中投加该复合菌群后,木薯酒精废液的COD去除率明显提高,达到90%以上.处理系统运行稳定.     

湘江干流水环境健康风险评价

为研究湘江水环境污染对人体健康产生的危害风险,在简要介绍健康风险评价方法及国内外研究、应用进展的基础上,建立了水环境健康风险评价模式,应用2000年的水质监测资料,对湘江干流主要断面进行了水环境健康风险评价.结果表明,在所评价断面中,非致癌物质由饮水途径所致健康危害的个人年风险按大小排列为Pb＞Hg＞NH3＞酚;化学致癌物质由饮水途径所致健康危害的个人年风险按大小排列为As＞Cd;化学致癌物质对人体健康危害的个人年风险远超过非致癌物质;污染最为严重的为松柏断面,其次是五星断面和三叉矶断面.湘江干流衡阳以上江段水质良好,衡阳以下江段水质较差.研究对湘江干流水污染防治方略的制定具有一定价值.     

模糊综合评价法在道路运输企业安全评价中的应用

我国道路运输企业交通安全形势比较严峻,推行道路运输企业安全综合评价是降低道路运输企业交通事故的有效途径之一.本文运用Delphi法和AHP法建立了道路运输企业安全层次分析模型,构建了安全综合评价指标体系.选用基于"差动"原理的赋权法--G1法计算各指标的权重,应用模糊综合评价法对其进行安全综合评价.采用平均加权法对评价因素的各项指标进行量化处理,从而得到道路运输企业安全的综合评价结果.最后,对陕西省一家道路运输企业进行了实际验证,比较真实地反映了此企业的安全状况.     

卷烟厂通风空调系统中聚积物燃烧特性研究

选取某烟厂车间通风空调系统,分别对风管内表面及设备部件表面附着的聚积物进行实测与分析.通过对所采集样品的C、H、N、S等的元素分析、工业分析、自然状态下的着火点参数以及灰熔融性参数等的实验分析,得到了烟厂建筑的通风空调系统中聚积物的燃烧特性,为工业建筑火灾的预测评价及防排烟设计提供了参考.     

基于模糊聚类关联分析法的煤与瓦斯突出程度分析

运用模糊聚类分析方法对煤与瓦斯突出的样本集合进行分类,建立了不同突出程度的模糊模式.用关联分析确定待分析样本与模式的关联程度,以此预测预报样本的煤与瓦斯突出危险程度.实例分析表明,与模糊聚类分类后、将模式与待预报样本组成新样本集合进行聚类分析并以此分类结果进行预报的方法相比,这种预报方法不仅可靠程度高,而且能定量描述待报样本与模式的亲和程度.     

生态缺水条件下流域生态经济系统安全性分析

生态用水和社会经济用水的竞争状况使得研究水资源短缺地区的流域生态经济系统安全状况、有效进行生态缺水条件下流域生态经济系统的调控十分必要.从宏观角度出发,首先分析了流域生态经济系统演化的机制和影响因素,在此基础上,通过建立指标体系,提出了构建流域主要指标为状态变量的生态经济系统演化模型,并利用模型进行系统安全性分析.以潮白河流域为例,构建了人口数量、人均GDP、生态系统指数以及生态用水比例为状态变量的生态经济系统演化模型.模型模拟结果表明,如果不加以调控,该流域将无法提供生态经济系统的安全保障.提出了提高生态用水比例、控制经济增长速度和积极进行生态建设、控制水土流失的对策,为实现潮白河流域的生态经济系统安全保障服务.     

1993-2003年特大火灾发生规律、特征及原因分析

火灾作为一种灾害现象,其发生与发展具有随机性和确定性的双重特性.火灾统计分析是研究火灾随机性规律的一种有效方法,它通过总结、整理和分析大量的原始火灾资料,归纳出火灾发生的统计性规律.本文从1993-2003年我国火灾形势着手,联系火灾形势发展过程中的火灾起数、火灾中人员伤亡和直接财产损失等大量数据,重点分析了特大火灾的原因及类别特征,总结了特大火灾发生发展的规律和趋势,为正确认识和预测我国火灾形势、做好特大火灾的预防工作提供了参考.     

改善太仓城区水环境原型调水实验研究及模型建立

为达到改善太仓城区水环境的目的,于2004年4月21日进行了调水实验.调水历时14 h,期间向城区调水21.8万m3.通过对监测点采样,得到水量、水质实测数据.根据实验数据,建立了符合太仓河网的水量水质数学模型,分析了从长江引水对太仓城区水环境的改善程度.同时对不同引水方案情况下城区水环境改善效果,以及截污和清淤对水环境的影响做了分析.研究表明,引水只能短期改善水环境;要根治水环境,必须从源头抓起,进行截污.